Iron Ore / Ironstone Concretion
Mixture of iron oxide/hydroxide minerals, likely some combination of Hematite (Fe2O3), Goethite (α-FeOOH), and Limonite (a general term for hydrated iron oxides of variable composition) or potentially Bauxite (a mixture of aluminum hydroxides, often with iron oxides, (Al(OH)3) and FeO(OH)). The visual characteristics strongly suggest iron-rich material.